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Drying of chemical compounds in solution or suspension

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An introduction to the case study

Drying stands as a pivotal process for the production of high-purity powders derived from chemical compounds in solution or suspension. Examples of such compounds encompass calcium carbonate, aluminum hydroxide, calcium nitrate, magnesium sulfate, magnesium carbonate, copper sulfate, dicalcium phosphate, ammonium sulfate and phosphate, calcium carbonate and phosphate, as well as boric and adipic acids, among others.

Among the various techniques available, spray drying emerges as the predominant method for converting these chemical compound solutions or suspensions into fine powders. However, when compared to spray drying, pulse combustion drying consistently yields superior powders in terms of particle morphology, size, and powder flowability.

Look at how we deal with the followingchallenges:

Drying of chemical compounds in solution or suspension
BSY

Challenge:

In industrial processes, powders are often preferred to possess spherical particles with a narrow size distribution and controllable morphology. This applies both to their use as raw materials in production and as final products, where particle size plays a crucial role.

The major challenge associated with spray drying lies in the unpredictability of powder particle morphology post-drying. It can result in undesirable forms, such as hollow or toroidal-like spheres, or even doughnut-shaped particles. Furthermore, in certain medical applications, the requirement for powders with submicron particles exceeds the capabilities of spray drying.

Solution:

Sinowatek's advanced pulse combustion drying technology offers a solution that surpasses spray drying in multiple aspects. The powders produced are superior due to their predictable formation of smooth, spherical solid particles, submicron-sized particles, a narrow particle size distribution, and excellent powder flowability.

These superior properties arise from gas-dynamic atomization occurring at the top of the drying chamber. Here, a low-pressure, slow-moving liquid solution or suspension is introduced through a single pipe into a pulsating, high-velocity gas stream. Within milliseconds, this process forms ultra-fine (5-50μm) droplets while converting the surface moisture into superheated steam. The result is a dry, fine powder with spherical and smooth surface particles. The energy absorbed by the evaporating water and the extremely short time the solids are exposed to the heat source, ensure the preservation of the characteristics of the solids.

Benefits for clients:

  • Energy consumption for PCD dryers stands at 1.15 kW/kg water evaporated (thermal and electric). In contrast, studies indicate that spray drying processes can consume as much as 2.3 kW/kg (equivalent to 8.4 GJ/metric ton). Pulse Combustion Dryers demand less air, resulting in smaller drying chambers and reduced electrical consumption for smaller fans. With simple product injectors and smaller fans, running costs are 20-30% lower than those of spray driers.
  • Unlike spray dryers, the PCD boasts an atomization nozzle that essentially functions as an open pipe, eliminating concerns about wear and tear affecting atomization dynamics.
  • The PCD employs no high-pressure pumps or high-RPM equipment, resulting in lower maintenance requirements compared to its competitors.
  • Smaller air volumes, lower pressure for mixture delivery, and a more compact equipment footprint collectively make the process more cost-effective than traditional spray drying methods.
  • Sinowatek's Pulse Combustion Dryer (PCD) Test Centre offers the capability to dry any chemical compound in solution or suspension for suitability and compatibility assessments with the drying method. This process also validates energy consumption and product quality parameters, guiding the design and construction of scaled-up production PCD units.
  • For low-volume toll processing needs, we provide access to our PC Dryer at the PCD test centre, facilitating the drying of high-value, high-purity products.
BSY
BSY
BSY
BSY

1. Brewer’s spent yeast (BSY) drying

BSY

Drying of chemical compounds in solution or suspension

Challenge:

In industrial processes, powders are often preferred to possess spherical particles with a narrow size distribution and controllable morphology. This applies both to their use as raw materials in production and as final products, where particle size plays a crucial role.

The major challenge associated with spray drying lies in the unpredictability of powder particle morphology post-drying. It can result in undesirable forms, such as hollow or toroidal-like spheres, or even doughnut-shaped particles. Furthermore, in certain medical applications, the requirement for powders with submicron particles exceeds the capabilities of spray drying.

Solution:

Sinowatek's advanced pulse combustion drying technology offers a solution that surpasses spray drying in multiple aspects. The powders produced are superior due to their predictable formation of smooth, spherical solid particles, submicron-sized particles, a narrow particle size distribution, and excellent powder flowability.

These superior properties arise from gas-dynamic atomization occurring at the top of the drying chamber. Here, a low-pressure, slow-moving liquid solution or suspension is introduced through a single pipe into a pulsating, high-velocity gas stream. Within milliseconds, this process forms ultra-fine (5-50μm) droplets while converting the surface moisture into superheated steam. The result is a dry, fine powder with spherical and smooth surface particles. The energy absorbed by the evaporating water and the extremely short time the solids are exposed to the heat source, ensure the preservation of the characteristics of the solids.

Benefits for clients:

  • Energy consumption for PCD dryers stands at 1.15 kW/kg water evaporated (thermal and electric). In contrast, studies indicate that spray drying processes can consume as much as 2.3 kW/kg (equivalent to 8.4 GJ/metric ton). Pulse Combustion Dryers demand less air, resulting in smaller drying chambers and reduced electrical consumption for smaller fans. With simple product injectors and smaller fans, running costs are 20-30% lower than those of spray driers.
  • Unlike spray dryers, the PCD boasts an atomization nozzle that essentially functions as an open pipe, eliminating concerns about wear and tear affecting atomization dynamics.
  • The PCD employs no high-pressure pumps or high-RPM equipment, resulting in lower maintenance requirements compared to its competitors.
  • Smaller air volumes, lower pressure for mixture delivery, and a more compact equipment footprint collectively make the process more cost-effective than traditional spray drying methods.
  • Sinowatek's Pulse Combustion Dryer (PCD) Test Centre offers the capability to dry any chemical compound in solution or suspension for suitability and compatibility assessments with the drying method. This process also validates energy consumption and product quality parameters, guiding the design and construction of scaled-up production PCD units.
  • For low-volume toll processing needs, we provide access to our PC Dryer at the PCD test centre, facilitating the drying of high-value, high-purity products.

2. Brewer’s spent grain

Spent Grain

Brewer’s spent grain

The challenge:

Brewer’s spent grain is most often sold as animal feed due to its properties and content of essential nitrogen-containing nutrients. The high moisture content (80%-90%) of this process waste makes it susceptible to microbial growth in the usual environmental conditions prevailing on farms. Within a few days after production, wet grain can undergo molding and spoiling. Therefore, dewatering and treatment for mold prevention are key factors in the utilization of this process waste.

The solution:

Sinowatek offers the Fournier Rotary PressTM dewatering technology for reducing the moisture content from the spent grain slurry. The rotary press produces a high level of cake dryness and competitive production rates.

Benefit for the client:

  • The dewatering can preserve the BSG and is a key factor in the utilization of the by-product as animal feed.
  • The dryer waste has a lighter weight, resulting in lower transport costs.

3. Spent Kieselguhr slurry

Kieselguhr

Spent Kieselguhr slurry

The challenge:

Kieselguhr (Diatomaceous Earth) is a chalk-like sedimentary mineral derived from fossilized shell-like remains of marine algae called diatoms. The shells are extremely fine and generally range in length from 40 to 160 μm and in width from 2 to 5 μm, the latter being roughly the diameter of most yeast cells. Because of their microscopic size and porous nature, Kieselguhr has been used extensively in the brewing industry as a filtering medium.

Due to the retention of organic material, especially yeast, proteins, and polyphenols by the end of the filtration, cake mass can be increased three times or more. Kieselguhr is a single-use product before being discarded due to its saturation.

The used kieselguhr is a slurry with a water content of 80-90 % creating a process waste that requires environmentally conscience disposal or recycling.

The solution:

Discarded kieselguhr is stored in a tank capable of keeping the slurry (TS around 3%) in suspension before being routed through a Fournier Rotary PressTM where it is dewatered to a cake dryness of 35% TS, ready for disposal or recycling.

Benefit for the client:

  • The Fournier Rotary PressTM ensures high consistency and good cake dryness using very little electrical power while operating unsupervised.
  • The high capture rate of suspended solids reduces the BOD of water going to the wastewater treatment plant.
  • The dryer waste has a lighter weight, resulting in lower transport costs.
  • The Rotary Press is an expandable technology, allowing channels to be added to the unit to accommodate future increases in sludge quantities. Provision can be made to expand a rotary press to 8 channels as demand increases.

4. Bottle washing and filling plant

Beer Bottles

Bottle washing and filling plant

The challenge:

Filling is the last step of the beer brewing process and the first step of the packaging. Sanitary conditions at this stage have a direct impact on the shelf life of bottled beer.

The beer producers endeavour to deliver pure, fresh, tasty, and natural beverages with a long minimum shelf life with no preservatives or additional thermal treatment. Other marketing challenges are the variety of containment materials (glassware, PET, tinplate/aluminium, or the inside coated cardboard boxes) and long distribution paths.

Industrial sanitation (washing and disinfection) of the whole filling line is therefore a top priority in the industrial hygiene of beverage production.

With the conventional cleaning operating technology, the filler is emptied and flushed, disinfected, flushed again and afterwards re-filled. The complete cleaning procedure is therefore very time-consuming, cost-intensive and reduces the plant productivity.

An assortment of chemicals is used for aseptic filling or traditional custom filling. These chemicals cause high wear and corrosion of the filling equipment.

The solution:

Sinowatek offers the INNOWATECH Anolyte® for the disinfection of filler equipment e.g. rinser, filler, bottle washer etc. INNOWATECH Anolyte® tradename SulafectTM is produced electrolytically from a high pure aqueous salt solution on-site with the Aquadron® system.

The disinfectant differs in its physical properties (colour, specific weight, density, viscosity, melting and freezing point) not much from pure water, as it contains only a low concentration of free chlorine. INNOWATECH Anolyte® tradename SulafectTM is a pH neutral, bactericidal, virucidal and fungicidal solution. Because of its low application concentration, it is odourless and tasteless, and, unlike traditional chlorine or chlorine dioxide disinfectants, it is gentle on materials it comes into contact with.

SulafectTM operates at lower concentrations but achieves higher germ-killing rates than conventional disinfectants. It effectively kills legionella, pseudomonads, and other germs, which can be especially prevalent in natural drink products. In addition, while preventing the formation of new ones.

With the bottle shower and SulafectTM system, disinfection of the filler table and surrounding areas is performed continuously. Thus, interruptions of production for in-between cleanings and disinfection can be avoided. The productivity of the plant increases, and water consumption is reduced.

The Aquadron® systems and the active agent Anolyte® (SulafectTM) have already proven reliable in the beer brewing industry for years.

The benefit to the client:

Main advantages of using SulafectTM as a disinfectant:

  • Safe and quick elimination of all germs.
  • Better microbiological control.
  • Complete replacement of all chemicals used for conventional disinfection.
  • Short exposure times (5 min.) for full impact.
  • No re-contamination by rinse water residues.
  • Safe application in the production, filling, and packaging department, with no corrosion on stainless steel and no wear on elastomers.


Main advantages of using the Aquadron® system:

  • Handling and storage of dangerous chemicals or substances is eliminated.
  • Due to the neutral pH no wastewater pollution.
  • Reduction of AOX/COD – values in the wastewater plant
  • Low operation and maintenance costs,
  • For the operation only high-quality salt and electricity are needed.
  • Reduced water consumption due to less cleaning and disinfection flushing.
  • Easy operation with an intuitive user interface.
  • Minimised storage and logistic costs.
  • Uncomplicated integration into existing systems.
  • Short installation and start-up time.
  • With this technology beverages can be filled in their natural form without adding any preservatives.
  • Reduction of operating costs while achieving high hygienic standards.

5. CIP system water treatment

CIP System

CIP system water treatment

The challenge:

In the brewing industry, impeccable hygiene is an essential precondition for making final products of consistently high quality and a long shelf life. A highly efficient CIP process in beer breweries is therefore non-negotiable.

The cleaning and disinfectant agents in conventional CIP stations are expensive and the CIP process requires a lot of time and effort. Materials are subject to rigid safety regulations for storage, handling, and disposal.

These agents kill germs aggressively while impacting the life of pipes and valves. Proactive thermal disinfection, as an alternative to chemicals, is also time-consuming and not always effective.

The solution:

Sinowatek offers the INNOWATECH Anolyte® for the CIP system of a brewery. INNOWATECH Anolyte® tradename SulafectTM is produced electrolytically from a high pure aqueous salt solution on-site with the Aquadron® system.

The disinfectant differs in its physical properties (colour, specific weight, density, viscosity, melting and freezing point) not much from pure water, as it contains a very low concentration of free chlorine. INNOWATECH Anolyte® tradename SulafectTM is pH neutral, bactericidal, virucidal and fungicidal. Because of its low application concentration, it is odourless and tasteless, and, unlike traditional chlorine or chlorine dioxide disinfectants, it is gentle on materials it comes in contact with.

Although SulafectTM operates at lower concentrations it achieves higher germ-killing rates than conventional disinfectants. It effectively kills legionella, pseudomonads, and other germs, which can be especially prevalent in natural drink products.

Using the INNOWATECH Anolyte® (SulafectTM)system in the CIP plant gives rise to high disinfection activity. Individual programme steps such as acid treatment after the main cleaning step or fresh water rinsing after disinfection can be completely eliminated.

The Aquadron® systems and the active agent Anolyte® have already proven reliable in the beer brewing industry over an extended period.

Benefit to the client:

Disinfection of CIP plants by INNOWATECH Anolyte® system replaces aggressive disinfection chemicals and saves water.

  • Reduction of costs for disinfectant.
  • Savings of rinsing water > 30%
  • Improved AOX and CSB values in wastewater.
  • Stack water tanks free of germs
  • Elimination of acid treatment in the cleaning cycle.
  • Elimination of annual tank cleaning against residue film formation.
  • Rinse water tests show no microbiological activity.

Let's talk  about your specific challenges in this field.